Production of H2 at Fast Rates Using a Nickel Electrocatalyst in Water/Acetonitrile Solutions

Production of H2 at Fast Rates Using a Nickel Electrocatalyst in Water/Acetonitrile Solutions:

Chem. Commun., 2013, Accepted Manuscript
DOI: 10.1039/C3CC43203C, Communication

Wesley A Hoffert, John A. S. Roberts, R Morris Bullock, Monte L Helm
We report a synthetic nickel complex containing proton relays, [Ni(P^Ph₂N^C6H4OH₂)₂](BF₄)₂ (P^Ph₂N^C6H4OH₂ = 1,5-bis(p-hydroxyphenyl)-3,7-diphenyl-1,5-diaza-3,7-diphosphacyclo-octane), that catalyzes the production of H₂ in aqueous acetonitrile with turnover frequencies of 750-170,000 s^-1 at directly...
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Synthesis and Reactivity of Silyl Iron, Cobalt, andNickel Complexes Bearing a [PSiP]-Pincer Ligand via Si–H BondActivation

Synthesis and Reactivity of Silyl Iron, Cobalt, and
Nickel Complexes Bearing a [PSiP]-Pincer Ligand via Si–H Bond
Activation:

Organometallics

DOI: 10.1021/om400047j

Carbon Monoxide Induced Reductive Elimination of Disulfidein an N-Heterocyclic Carbene (NHC)/ Thiolate Dinitrosyl IronComplex (DNIC)

Carbon Monoxide Induced Reductive Elimination of Disulfide
in an N-Heterocyclic Carbene (NHC)/ Thiolate Dinitrosyl Iron
Complex (DNIC):

Journal of the American Chemical Society

DOI: 10.1021/ja403916v

Catalytic Hydrogen Oxidation: Dawn of a New Iron Age

Catalytic Hydrogen Oxidation: Dawn of a New Iron Age:

One metal or two? Recent results in the design of hydrogenase mimics have resulted in NiFe- and Fe-based complexes (see picture) that split molecular H₂ into electrons and protons. Although these compounds are still far from technological application they improve our understanding of how nature exploits abundant metals to achieve complex reactions.

InelasticX-ray Scattering of a Transition-Metal Complex (FeCl4–): Vibrational Spectroscopy for All Normal Modes

Inelastic
X-ray Scattering of a Transition-Metal Complex (FeCl4–): Vibrational Spectroscopy for All Normal Modes:

Inorganic Chemistry

DOI: 10.1021/ic400353j

Catalytic CO2 Activation Assisted by RheniumHydride/B(C6F5)3 Frustrated LewisPairsMetal Hydrides Functioning as FLP Bases

Catalytic CO2 Activation Assisted by Rhenium
Hydride/B(C6F5)3 Frustrated Lewis
PairsMetal Hydrides Functioning as FLP Bases:

Journal of the American Chemical Society

DOI: 10.1021/ja402381d

A Novel Acylmethylpyridinol Ligand Containing DinuclearIron Complex Closely Related to [Fe]-Hydrogenase

A Novel Acylmethylpyridinol Ligand Containing Dinuclear
Iron Complex Closely Related to [Fe]-Hydrogenase:

Organometallics

DOI: 10.1021/om400240e