Monday, November 25, 2013

Earth-abundant hydrogen evolution electrocatalysts




Chem. Sci. , 2014, Advance Article

DOI: 10.1039/C3SC51711J, Minireview

James R. McKone, Smaranda C. Marinescu, Bruce S. Brunschwig, Jay R. Winkler, Harry B. Gray

Splitting water to hydrogen and oxygen is a promising approach for storing energy from intermittent renewables, such as solar power.

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Heterobimetallic Complexes of Polypyridyl Ligands Containing Paramagnetic Centers: Synthesis and Characterization by IR and EPR

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Inorganic Chemistry

DOI: 10.1021/ic401952s






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Synthesis and Reactivity of Two-Coordinate Ni(I) Alkyl and Aryl Complexes

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Journal of the American Chemical Society

DOI: 10.1021/ja4095236






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Thursday, November 21, 2013

Theoretical 57Fe Mössbauer Spectroscopy for Structure Elucidation of [Fe] Hydrogenase Active Site Intermediates

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Inorganic Chemistry

DOI: 10.1021/ic4021349






from Inorganic Chemistry: Latest Articles (ACS Publications) http://dx.doi.org/10.1021/ic4021349

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Tuesday, November 12, 2013

Thursday, November 7, 2013

Enhanced Photochemical Hydrogen Production by a Molecular Diiron Catalyst Incorporated into a Metal–Organic Framework

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Journal of the American Chemical Society

DOI: 10.1021/ja407176p






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Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction

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Journal of the American Chemical Society

DOI: 10.1021/ja407115p






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Enhanced Photochemical Hydrogen Production by a Molecular Diiron Catalyst Incorporated into a Metal–Organic Framework

TOC Graphic


Journal of the American Chemical Society

DOI: 10.1021/ja407176p






from Journal of the American Chemical Society: Latest Articles (ACS Publications) http://dx.doi.org/10.1021/ja407176p

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Earth-Abundant Hydrogen Evolution Electrocatalysts

Chem. Sci. , 2013, Accepted Manuscript

DOI: 10.1039/C3SC51711J, Minireview

James R McKone, Smaranda C. Marinescu, Jay Winkler, Bruce S Brunschwig, Harry Gray

Splitting water to hydrogen and oxygen is a promising approach for storing energy from intermittent renewables, such as solar power. Efficient, scalable solar water splitting devices require active and electrocatalysts...

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Towards [NiFe]-hydrogenase biomimetic models that couple H2 binding with functionally relevant intramolecular electron transfers: a quantum chemical study

Dalton Trans. , 2013, Accepted Manuscript

DOI: 10.1039/C3DT50836F, Paper

Claudio Greco

[FeFe]- and [NiFe]-hydrogenases are dihydrogen-evolving metalloenzymes that share striking structural and functional similarities, despite being phylogenetically unrelated. Most notably, they are able to combine substrate binding and redox functionalities, which...

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