Friday, June 24, 2011

Interfacial Photoreduction of Supercritical CO2 by an Aqueous Catalyst

Interfacial Photoreduction of Supercritical CO2 by an Aqueous Catalyst: "Thumbnail image of graphical abstract

No just a solvent anymore: CO2 reduction under supercritical conditions was achieved in a biphasic water–supercritical CO2 system using an aqueous soluble catalyst (see picture). The introduction of such an interface provides a suitable reaction medium where adsorption, CO2 binding, and protonation of intermediates are intimately linked.

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