Kinetics of oxidation of nitrosodisulfonate anion radical with a metallo-superoxide

Kinetics of oxidation of nitrosodisulfonate anion radical with a metallo-superoxide:

Dalton Trans., 2012, Advance Article DOI: 10.1039/C2DT12019D, Paper

Kaustab Mandal, Rupendranath Banerjee
Cobalt(III)-bound superoxide (1) forms a spin adduct with nitrosodisulfonate anion radical (NDS^2-) and oxidizes it by two electrons. Towards 1, NDS^2- is a kinetically controlled product and its further oxidation lowers the yield.