Efficient [FeFe] Hydrogenase Mimic Dyads Covalently Linking to Iridium Photosensitizer for Photocatalytic Hydrogen Evolution

Efficient [FeFe] Hydrogenase Mimic Dyads Covalently Linking to Iridium Photosensitizer for Photocatalytic Hydrogen Evolution:

Dalton Trans., 2012, Accepted Manuscript
DOI: 10.1039/C2DT31618H, Paper

Hong-hua Cui
Two [FeFe] hydrogenase mimics, [Fe2([small mu ]-pdt)(CO)5L1] (L1 = PPh2SPhNH2) (Ph = phenyl)) (2), [Fe2([small mu ]-pdt)(CO)5L2] (L2 = PPh2PhNH2) (3) and two molecular photocatalysts, [(CO)5([small mu ]-pdt)Fe2PPh2SPhNHCO(bpy)(ppy)2Ir]PF6 (bpy = bipyridine, ppy = 2-phenylpyridine) (2a) and...
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