Dalton Trans., 2013, Advance Article
DOI: 10.1039/C2DT32008H, Paper
DOI: 10.1039/C2DT32008H, Paper
Robert Beck, Manar Shoshani, Jonathan Krasinkiewicz, Jillian A. Hatnean, Samuel A. Johnson
The Ni(I) complexes (iPr3P)2NiX (3a-c), (where X = Cl, Br, I) and Ni(0) dinitrogen complex [(iPr3P)2Ni]2([small mu ]-[small eta]1:[small eta]1-N2) (5) serve as convenient precursors for complexes such as (iPr3P)2Ni([small eta]2-CO2) (7), [(iPr3P)Ni([small mu ]-[small eta]1:[small eta]2-CS2)]2 (9), [(iPr3P)Ni([small mu ]2-PPh2)]2 (10), (iPr3P)2Ni(SPh)(H) (11) and [(iPr3P)Ni([small mu ]2-SPh)]2 (12).
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The Ni(I) complexes (iPr3P)2NiX (3a-c), (where X = Cl, Br, I) and Ni(0) dinitrogen complex [(iPr3P)2Ni]2([small mu ]-[small eta]1:[small eta]1-N2) (5) serve as convenient precursors for complexes such as (iPr3P)2Ni([small eta]2-CO2) (7), [(iPr3P)Ni([small mu ]-[small eta]1:[small eta]2-CS2)]2 (9), [(iPr3P)Ni([small mu ]2-PPh2)]2 (10), (iPr3P)2Ni(SPh)(H) (11) and [(iPr3P)Ni([small mu ]2-SPh)]2 (12).
To cite this article before page numbers are assigned, use the DOI form of citation above.
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