Formationof [NiIII(κ1-S2CH)(P(o-C6H3-3-SiMe3-2-S)3)]− via CS2 Insertioninto Nickel(III) HydrideContaining [NiIII(H)(P(o-C6H3-3-SiMe3-2-S)3)]−

Formation
of [NiIII(κ1-S2CH)(P(o-C6H3-3-SiMe3-2-S)3)]− via CS2 Insertion
into Nickel(III) Hydride
Containing [NiIII(H)(P(o-C6H3-3-SiMe3-2-S)3)]−:

Inorganic Chemistry

DOI: 10.1021/ic400293k

Stoichiometric Metal-Free Reduction of CO in Syn-Gas

Stoichiometric Metal-Free Reduction of CO in Syn-Gas:

Journal of the American Chemical Society

DOI: 10.1021/ja401492s

Monomeric Rhodium(II) Complexes Supported by a Diarylamido/Bis(phosphine)PNP PincerLigand and Their Reactivity Toward Dihydrogen

Monomeric Rhodium(II) Complexes Supported by a Diarylamido/Bis(phosphine)
PNP Pincer
Ligand and Their Reactivity Toward Dihydrogen:

Organometallics

DOI: 10.1021/om300760j

Mechanistic Studies on Proton Transfer in a [FeFe] Hydrogenase Mimic Complex

Mechanistic Studies on Proton Transfer in a [FeFe] Hydrogenase Mimic Complex:

, 2013, Accepted Manuscript
DOI: 10.1039/C3DT33087G, Paper

Marten Ahlquist, Ying Wang
Four different pathways for deprotonation of [([small mu ]-pdt){Fe(CO)3}{Fe(CO)([small kappa]2-Me2PCH2N(Me)CH2PMe2)}] (pdt = propane-1,3-dithiolate) [1H]1+ were examined, including 1) the "Direct" deprotonation; 2) the "Indirect" deprotonation via the pendant amine N; 3) the "Indirect"...
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Protonationof Ferrous Dinitrogen Complexes Containinga Diphosphine Ligand with a Pendent Amine

Protonation
of Ferrous Dinitrogen Complexes Containing
a Diphosphine Ligand with a Pendent Amine:

Inorganic Chemistry

DOI: 10.1021/ic4000704

Direct Determination ofEquilibrium Potentials for Hydrogen Oxidation/Production by Open CircuitPotential Measurements in Acetonitrile

Direct Determination of
Equilibrium Potentials for Hydrogen Oxidation/Production by Open Circuit
Potential Measurements in Acetonitrile:

Inorganic Chemistry

DOI: 10.1021/ic302461q

1,2-Disubstituted Aryl-Based Ferrocenyl Phosphines

1,2-Disubstituted Aryl-Based Ferrocenyl Phosphines:

Organometallics

DOI: 10.1021/om400117n

Synthesis of Coordinatively Unsaturated Half-Sandwich Iron–Silyl Complexes with an N-Heterocyclic Carbene Ligand and Their Reactions with H2

Synthesis of Coordinatively Unsaturated Half-Sandwich Iron–Silyl Complexes with an N-Heterocyclic Carbene Ligand and Their Reactions with H2:

Abstract

A half-sandwich, coordinatively unsaturated N-heterocyclic carbene complex of iron with a metallacycle was found to cleave the Si–H bonds of hydrosilanes to give 16-electron iron–silyl complexes. The reactions of silyl complexes with H₂ led to the formation of dihydride complexes, in which hydride ligands weakly interact with the silicon atom. The molecular structures of these new complexes have been determined by means of X-ray crystallography.

A half-sandwich, 16-electron iron complex with a cyclometalated N-heterocyclic carbene ligand was found to activate the Si–H bonds of hydrosilanes, thus giving rise to coordinatively unsaturated iron–silyl complexes. The silyl complexes interact with H₂ to form 18-electron dihydride complexes.

Oxo–Mo(IV)(dithiolene)thiolatoComplexes: Analogue of Reduced Sulfite Oxidase

Oxo–Mo(IV)(dithiolene)thiolato
Complexes: Analogue of Reduced Sulfite Oxidase:

Inorganic Chemistry

DOI: 10.1021/ic302485c

Iron ina Trigonal Tris(alkoxide) Ligand Environment

Iron in
a Trigonal Tris(alkoxide) Ligand Environment:

Inorganic Chemistry

DOI: 10.1021/ic302634q

Cobalt Corrole Catalystfor Efficient Hydrogen Evolution Reaction from H2O underAmbient Conditions: Reactivity, Spectroscopy, and Density FunctionalTheory Calculations

Cobalt Corrole Catalyst
for Efficient Hydrogen Evolution Reaction from H2O under
Ambient Conditions: Reactivity, Spectroscopy, and Density Functional
Theory Calculations:

Inorganic Chemistry

DOI: 10.1021/ic4000473

A Transition Metal Lewis Acid/Base Triad System forCooperative Substrate Binding

A Transition Metal Lewis Acid/Base Triad System for
Cooperative Substrate Binding:

Journal of the American Chemical Society

DOI: 10.1021/ja400962h

High Catalytic Rates forHydrogen Production UsingNickel Electrocatalysts with Seven-Membered Cyclic Diphosphine LigandsContaining One Pendant Amine

High Catalytic Rates for
Hydrogen Production Using
Nickel Electrocatalysts with Seven-Membered Cyclic Diphosphine Ligands
Containing One Pendant Amine:

Journal of the American Chemical Society

DOI: 10.1021/ja400181a

Steady-State Catalytic Wave-Shapes for 2-ElectronReversible Electrocatalysts and Enzymes

Steady-State Catalytic Wave-Shapes for 2-Electron
Reversible Electrocatalysts and Enzymes:

Journal of the American Chemical Society

DOI: 10.1021/ja311607s

Insights into the Interplay of Lewis and BrønstedAcid Catalysts in Glucose and Fructose Conversion to 5-(Hydroxymethyl)furfuraland Levulinic Acid in Aqueous Media

Insights into the Interplay of Lewis and Brønsted
Acid Catalysts in Glucose and Fructose Conversion to 5-(Hydroxymethyl)furfural
and Levulinic Acid in Aqueous Media:

Journal of the American Chemical Society

DOI: 10.1021/ja3122763

Steady-State Catalytic Wave-Shapes for 2-ElectronReversible Electrocatalysts and Enzymes

Steady-State Catalytic Wave-Shapes for 2-Electron
Reversible Electrocatalysts and Enzymes:

Journal of the American Chemical Society

DOI: 10.1021/ja311607s

Insights into the Interplay of Lewis and BrønstedAcid Catalysts in Glucose and Fructose Conversion to 5-(Hydroxymethyl)furfuraland Levulinic Acid in Aqueous Media

Insights into the Interplay of Lewis and Brønsted
Acid Catalysts in Glucose and Fructose Conversion to 5-(Hydroxymethyl)furfural
and Levulinic Acid in Aqueous Media:

Journal of the American Chemical Society

DOI: 10.1021/ja3122763

Models of the iron-only hydrogenase: A comparison of chelate and bridge isomers of Fe2(CO)4{Ph2PN(R)PPh2}(-pdt) as proton-reduction catalysts

Models of the iron-only hydrogenase: A comparison of chelate and bridge isomers of Fe2(CO)4{Ph2PN(R)PPh2}(-pdt) as proton-reduction catalysts:

, 2013, Accepted Manuscript
DOI: 10.1039/C3DT50147G, Paper

G Hogarth, Shishir Ghosh, Nathan Hollingsworth, Katherine B Holt, Idris Richards, Ben E Sanchez, David G Unwin, Michael G. Richmond
Reactions of Fe2(CO)6(-pdt) (pdt = SCH2CH2CH2S) with aminodiphosphines Ph2PN(R)PPh2 (R = allyl, iPr, iBu, p-tolyl, H) have been carried out under different conditions. At room temperature in MeCN with added...
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