Mechanistic Studies on Proton Transfer in a [FeFe] Hydrogenase Mimic Complex

Mechanistic Studies on Proton Transfer in a [FeFe] Hydrogenase Mimic Complex:

, 2013, Accepted Manuscript
DOI: 10.1039/C3DT33087G, Paper

Marten Ahlquist, Ying Wang
Four different pathways for deprotonation of [([small mu ]-pdt){Fe(CO)3}{Fe(CO)([small kappa]2-Me2PCH2N(Me)CH2PMe2)}] (pdt = propane-1,3-dithiolate) [1H]1+ were examined, including 1) the "Direct" deprotonation; 2) the "Indirect" deprotonation via the pendant amine N; 3) the "Indirect"...
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