Friday, April 12, 2013

Ferracyclic carbamoyl complexes related to the active site of [Fe]-hydrogenase

Ferracyclic carbamoyl complexes related to the active site of [Fe]-hydrogenase:
, 2013, Accepted Manuscript
DOI: 10.1039/C3DT50642H, Paper
Peter J Turrell, Amanda D Hill, Saad Khalil Ibrahim, Joseph A Wright, C J Pickett
The active site of the [Fe]-hydrogenase features an iron(II) centre bearing cis carbonyl groups and a chelating pyridine-acyl ligand. Reproducing these unusual features in synthetic models is an intriguing challenge,...
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