Evidence for acyl-iron ligation in the active site of [Fe]-hydrogenase provided by mass spectrometry and infrared spectroscopy

Evidence for acyl-iron ligation in the active site of [Fe]-hydrogenase provided by mass spectrometry and infrared spectroscopy:

Dalton Trans., 2012, Advance ArticleDOI: 10.1039/C1DT11093D, Paper

Seigo Shima, Michael Schick, Jorg Kahnt, Kenichi Ataka, Klaus Steinbach, Uwe Linne
MS and IR analyses provided strong evidence for the acyl-iron ligation in the iron guanylylpyridinol cofactor of [Fe]-hydrogenase.