Hydrolytic behaviour and chloride ion binding capability of [Ru([small eta]6-p-cym)(H2O)3]2+: a solution equilibrium study

Hydrolytic behaviour and chloride ion binding capability of [Ru([small eta]6-p-cym)(H2O)3]2+: a solution equilibrium study:

Dalton Trans., 2011, Advance Article DOI: 10.1039/C1DT11405K, Paper Linda Biro, Etelka Farkas, Peter Buglyo

The hydrolysis of [Ru([small eta]⁶-p-cym)(H₂O)₃]²⁺ in the presence of chloride ion was studied using combined pH-potentiometric, UV-VIS, NMR and ESI-MS techniques to estimate stoichiometry and thermodynamic stability constants of the complexes in aqueous solution.