Heterolytic activation of hydrogen using frustrated Lewis pairs containing tris(2,2[prime or minute],2[prime or minute][prime or minute]-perfluorobiphenyl)borane

Heterolytic activation of hydrogen using frustrated Lewis pairs containing tris(2,2[prime or minute],2[prime or minute][prime or minute]-perfluorobiphenyl)borane:

Dalton Trans., 2012, Advance Article
DOI: 10.1039/C2DT30334E, Paper

Samantha C. Binding, Hasna Zaher, F. Mark Chadwick, Dermot O'Hare
The bulky borane tris(2,2,2-perfluorobiphenyl)borane is crystallographically characterised, and is used with nitrogen based Lewis bases to synthesize novel 'frustrated Lewis pairs' that activate dihydrogen.
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