Substituent Effects on Ni-S Bond Dissociation Energies and Kinetic Stability of Nickel Arylthiolate Complexes Supported by a Bis(phosphinite)-Based Pincer Ligand

Substituent Effects on Ni-S Bond Dissociation Energies and Kinetic Stability of Nickel Arylthiolate Complexes Supported by a Bis(phosphinite)-Based Pincer Ligand:

Dalton Trans., 2012, Accepted Manuscript
DOI: 10.1039/C2DT30407D, Paper

Jie Zhang, Anubendu Adhikary, Krista M King, Jeanette Krause, Hairong Guan
Pincer complexes of the type [2,6-(R2PO)2C6H3]NiSC6H4Z (R = Ph and i-Pr; Z = p-OCH3, p-CH3, H, p-Cl, and p-CF3) have been synthesized from [2,6-(R2PO)2C6H3]NiCl and sodium arylthiolate. X-ray structure determinations...