The reactions of pyridinyl thioesters with triirondodecacarbonyl: their novel diiron carbonyl complexes and mechanistic investigations

The reactions of pyridinyl thioesters with triirondodecacarbonyl: their novel diiron carbonyl complexes and mechanistic investigations:

Dalton Trans., 2012, Accepted Manuscript
DOI: 10.1039/C2DT30798G, Paper

Xiaoming Liu, Giuseppe Zampella
Reaction of Fe3(CO)12 with pyridinyl thioester liagnd PyCH2SCOCH3 (L1, Py = pyridin-2-yl) produced complex, [Fe2([small kappa]-COCH3)([small mu ]-SCH2Py)(CO)5] (1) (PyCH2S = pyridin-2-ylmethanethiolate). When complex 1 reacted with PPh3, a monosubstituted complex, [Fe2([small kappa]-COCH3)([small mu ]-SCH2Py)(CO)4PPh3] (2),...
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