Selective Four Electron Reduction of O2 by an Iron Porphyrin Electrocatalyst Under Fast and Slow Electron Flux

Selective Four Electron Reduction of O2 by an Iron Porphyrin Electrocatalyst Under Fast and Slow Electron Flux:

Chem. Commun., 2012, Accepted Manuscript
DOI: 10.1039/C2CC32832A, Communication

Subhra Samanta, Kushal Sengupta, Kaustuv Mittra, Sabyasachi Bandyopadhay, Abhishek Dey
An iron porphyrin catalyst with four electron donor groups is reported. The porphyrin ligand bears a distal hydrogen bonding pocket which inverts the normal axial ligand binding selectivity exhibited by...