Biomimetic model for [FeFe]-hydrogenase: asymmetrically disubstituted diiron complex with a redox-active 2,2[prime or minute]-bipyridyl ligand

Biomimetic model for [FeFe]-hydrogenase: asymmetrically disubstituted diiron complex with a redox-active 2,2[prime or minute]-bipyridyl ligand:

Dalton Trans., 2013, Advance Article
DOI: 10.1039/C2DT32457A, Paper

Souvik Roy, Thomas L. Groy, Anne K. Jones
The ability of ([small mu ]-S(CH₂)₃S)Fe₂(CO)₄([small kappa]²-bpy) to electrocatalyze reduction of protons to hydrogen was characterized. The catalytic potential is higher than expected based on comparison to phosphine or N-heterocyclic carbene containing complexes.
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