Proton-coupled electron transfer at a [Co-OHx]z unit in aqueous media: evidence for a concerted mechanism

Proton-coupled electron transfer at a [Co-OHx]z unit in aqueous media: evidence for a concerted mechanism:

Chem. Sci., 2013, Advance Article
DOI: 10.1039/C2SC21419A, Edge Article

Derek J. Wasylenko, Heidi M. Tatlock, Luvdeep S. Bhandari, James R. Gardinier, Curtis P. Berlinguette
The proton-coupled electron transfer (PCET) chemistry associated with the [Co-OH]²⁺/[Co-OH₂]²⁺ redox couple for two cobalt complexes bearing pentadentate ligands is reported.
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