High Catalytic Rates forHydrogen Production UsingNickel Electrocatalysts with Seven-Membered Cyclic Diphosphine LigandsContaining One Pendant Amine

High Catalytic Rates for
Hydrogen Production Using
Nickel Electrocatalysts with Seven-Membered Cyclic Diphosphine Ligands
Containing One Pendant Amine:

Journal of the American Chemical Society

DOI: 10.1021/ja400181a

Acid-Induced Mechanism Change and Overpotential Decreasein Dioxygen Reduction Catalysis with a Dinuclear Copper Complex

Acid-Induced Mechanism Change and Overpotential Decrease
in Dioxygen Reduction Catalysis with a Dinuclear Copper Complex:

Journal of the American Chemical Society

DOI: 10.1021/ja312256u

High Catalytic Rates forHydrogen Production UsingNickel Electrocatalysts with Seven-Membered Cyclic Diphosphine LigandsContaining One Pendant Amine

High Catalytic Rates for
Hydrogen Production Using
Nickel Electrocatalysts with Seven-Membered Cyclic Diphosphine Ligands
Containing One Pendant Amine:

Journal of the American Chemical Society

DOI: 10.1021/ja400181a

A Metal–Metal Bond in the Light-Induced Stateof [NiFe] Hydrogenases with Relevance to Hydrogen Evolution

A Metal–Metal Bond in the Light-Induced State
of [NiFe] Hydrogenases with Relevance to Hydrogen Evolution:

Journal of the American Chemical Society

DOI: 10.1021/ja3115899

Metal-Free Hydrogenation of N-BasedHeterocycles

Metal-Free Hydrogenation of N-Based
Heterocycles:

Organometallics

DOI: 10.1021/om4000727

Low OxidationState Iron(0), Iron(I), and Ruthenium(0) Dinitrogen Complexes witha Very Bulky Neutral Phosphine Ligand

Low Oxidation
State Iron(0), Iron(I), and Ruthenium(0) Dinitrogen Complexes with
a Very Bulky Neutral Phosphine Ligand:

Inorganic Chemistry

DOI: 10.1021/ic3024953

Bio-Inspired Catalytic Imine Reduction by Rhodium Complexes with Tethered Hantzsch Pyridinium Groups: Evidence for Direct Hydride Transfer from Dihydropyridine to Metal-Activated Substrate

Bio-Inspired Catalytic Imine Reduction by Rhodium Complexes with Tethered Hantzsch Pyridinium Groups: Evidence for Direct Hydride Transfer from Dihydropyridine to Metal-Activated Substrate:

Inspired by Nature: A conceptually new design for a catalyst, combining a metal center abutted to an organic hydride donor, is demonstrated for the formate-driven transfer hydrogenation of imines under ambient conditions. A key step, transfer of hydride from the organohydride donor to the metal-polarized substrate, mirrors that in metallo-(de)hydrogenase enzymes.

Intermolecular β-HydrogenAbstraction in Ytterbium, Calcium, and Potassium Tris(dimethylsilyl)methylCompounds

Intermolecular β-Hydrogen
Abstraction in Ytterbium, Calcium, and Potassium Tris(dimethylsilyl)methyl
Compounds:

Organometallics

DOI: 10.1021/om3010299

Isolation and X-ray Crystal Structures of Triarylphosphine Radical Cations

Isolation and X-ray Crystal Structures of Triarylphosphine Radical Cations:

Journal of the American Chemical Society

DOI: 10.1021/ja4012113

Migration Insertion Polymerization (MIP) of Cyclopentadienyldicarbonyldiphenylphosphinopropyliron(FpP): A New Concept for Main Chain Metal-Containing Polymers (MCPs)

Migration Insertion Polymerization (MIP) of Cyclopentadienyldicarbonyldiphenylphosphinopropyliron
(FpP): A New Concept for Main Chain Metal-Containing Polymers (MCPs):

Journal of the American Chemical Society

DOI: 10.1021/ja400755e

An iron complex with pendent amines as a molecular electrocatalyst for oxidation of hydrogen

An iron complex with pendent amines as a molecular electrocatalyst for oxidation of hydrogen:

Nature Chemistry.
doi:10.1038/nchem.1571

Authors: Tianbiao Liu, Daniel L. DuBois & R. Morris Bullock
Electricity can be produced by the oxidation of hydrogen in fuel cells, but the best catalyst for this is platinum, a precious metal of low abundance. Now a molecular complex of iron, a very abundant, inexpensive metal, has been rationally designed for the oxidation of H2 at room temperature.

An iron complex with pendent amines as a molecular electrocatalyst for oxidation of hydrogen

An iron complex with pendent amines as a molecular electrocatalyst for oxidation of hydrogen:

Nature Chemistry 5, 228 (2013).
doi:10.1038/nchem.1571

Authors: Tianbiao Liu, Daniel L. DuBois & R. Morris Bullock
Electricity can be produced by the oxidation of hydrogen in fuel cells, but the best catalyst for this is platinum, a precious metal of low abundance. Now a molecular complex of iron, a very abundant, inexpensive metal, has been rationally designed for the oxidation of H2 at room temperature.

Iron-Catalyzed, Atom-Economical, Chemo- and Regioselective Alkene Hydroboration with Pinacolborane

Iron-Catalyzed, Atom-Economical, Chemo- and Regioselective Alkene Hydroboration with Pinacolborane:

Precious iron: A new PNN iron complex has been developed for use in an iron-catalyzed alkene hydroboration reaction under mild conditions. The environmentally friendly and earth-abundant iron catalyst system is superior to precious-metal systems in terms of efficiency and selectivity for α-olefin hydroborations with pinacolborane.

Efficient Oxidation of Methane to Methanol by Dioxygen Mediated by Tricopper Clusters

Efficient Oxidation of Methane to Methanol by Dioxygen Mediated by Tricopper Clusters:

TONs of copper fun: There is considerable interest in developing catalysts to harness the abundant natural supply of methane for various industrial applications. Two tricopper complexes capable of mediating efficient oxidation of methane to methanol under ambient conditions were tested: a biomimetic tricopper complex (see figure) and a tricopper-peptide species derived from the particulate methane monooxygenase (pMMO) protein.

Alkane Dehydrogenationby C–H Activation atIridium(III)

Alkane Dehydrogenation
by C–H Activation at
Iridium(III):

Organometallics

DOI: 10.1021/om301267c

Catalytic Water Oxidationby Mononuclear Ru Complexes with an Anionic Ancillary Ligand

Catalytic Water Oxidation
by Mononuclear Ru Complexes with an Anionic Ancillary Ligand:

Inorganic Chemistry

DOI: 10.1021/ic302446h

Carbonate-Templated Self-Assemblyof an Alkylthiolate-Bridged Cadmium Macrocycle

Carbonate-Templated Self-Assembly
of an Alkylthiolate-Bridged Cadmium Macrocycle:

Inorganic Chemistry

DOI: 10.1021/ic302740j

ligand for Ni for NiFe modesl

Inter- and IntramolecularInteractions in Triptycene-DerivedBisphosphite Hydroformylation Catalysts: Structures, Energies, andCaveats for DFT-Assisted Ligand Design

Inter- and Intramolecular
Interactions in Triptycene-Derived
Bisphosphite Hydroformylation Catalysts: Structures, Energies, and
Caveats for DFT-Assisted Ligand Design:

Organometallics

DOI: 10.1021/om301027x

Hydroxymethylfurfural,A Versatile Platform ChemicalMade from Renewable Resources

Hydroxymethylfurfural,
A Versatile Platform Chemical
Made from Renewable Resources:

Chemical Reviews

DOI: 10.1021/cr300182k

Characterization of [4Fe-4S]Cluster Vibrations andStructure in Nitrogenase Fe Protein at Three Oxidation Levels viaCombined NRVS, EXAFS, and DFT Analyses

Characterization of [4Fe-4S]
Cluster Vibrations and
Structure in Nitrogenase Fe Protein at Three Oxidation Levels via
Combined NRVS, EXAFS, and DFT Analyses:

Journal of the American Chemical Society

DOI: 10.1021/ja307027n

Activation of CO2 by phosphinoamide hafnium complexes

Activation of CO2 by phosphinoamide hafnium complexes:

Chem. Commun., 2013, Advance Article
DOI: 10.1039/C3CC38286A, Communication

Michael J. Sgro, Douglas W. Stephan
Hf-phosphinoamide cation complexes behave as metal-based frustrated Lewis pairs and bind one or two equivalent of CO₂ and in as well can activate CO₂ in a bimetallic fashion to give a pseudo-tetrahedral P₂CO₂ fragment linking two Hf centres.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry