Five plus H2 gives four: UV irradiation of a bis(amidinate) complex with a [(H)Mo![[QUAD BOND]](https://lh3.googleusercontent.com/blogger_img_proxy/AEn0k_s-1lObXV_6mxo3GPysi22ntOzLCtTN76x1gOUDMJwXKDD2juoRx7x0U7WCb2bGUwrNYs-nMhDaAeIHYDdBJUBf5NAh-IGJ9tV_G_u0qQdhPSCY5vLI4wjej6LFO6bZVYJU9Ye8hNJBESO8=s0-d)
Mo(H)] core induces reductive elimination of H2 and formation of a known quintuply bonded Mo![[BOND]](https://lh3.googleusercontent.com/blogger_img_proxy/AEn0k_um-OrUfjIv5HkP1eXfclCn76cRm7XCmy1Q4hajMQuzT-qog0R7p2f6ceUBYFS-YTKWV7IZYXvslZ1eM0s_kBxPxHVvuqui6Ry1tXVr54--UiKbLMeITg9_eb4KRC1r7hiCtDJGL3pXykI2ZA=s0-d)
Mo species (see scheme) that reacts back with H2 to restore [(H)MoMo(H)]. UV irradiation of the bis(hydride) species in benzene and toluene gives arene complexes in which the aromatic hydrocarbon bridges the molybdenum atoms. Dipp=2,6-diisopropylphenyl.
Mo(H)] core induces reductive elimination of H2 and formation of a known quintuply bonded MoMo species (see scheme) that reacts back with H2 to restore [(H)MoMo(H)]. UV irradiation of the bis(hydride) species in benzene and toluene gives arene complexes in which the aromatic hydrocarbon bridges the molybdenum atoms. Dipp=2,6-diisopropylphenyl.
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