Tuesday, February 19, 2013

Iron-Catalyzed, Atom-Economical, Chemo- and Regioselective Alkene Hydroboration with Pinacolborane

Iron-Catalyzed, Atom-Economical, Chemo- and Regioselective Alkene Hydroboration with Pinacolborane: Thumbnail image of graphical abstract
Precious iron: A new PNN iron complex has been developed for use in an iron-catalyzed alkene hydroboration reaction under mild conditions. The environmentally friendly and earth-abundant iron catalyst system is superior to precious-metal systems in terms of efficiency and selectivity for α-olefin hydroborations with pinacolborane.

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