Taking the fizz out: A digermyne compound with a Ge![[BOND]](https://lh3.googleusercontent.com/blogger_img_proxy/AEn0k_tWvdRNc7hxJi4oQPW3TDdBRkoLrLUzIH0QWALOXWQsWuD4lwog26wPdYBe3H7GjYB_ah3ciFwo8ltSh1DmnSfRnOZpOYU29Xq6izbAPKrCZbn2nv0hl8oVQ_BuZfcNp8vqHdWBCRuRXiTU6w=s0-d)
Ge single bond has been shown to quantitatively reduce CO2 to CO at temperatures as low as −40 °C. The mechanism of this unprecedented reaction has been probed by spectroscopic and computational techniques and involves a metastable intermediate (see picture, Ar*=C6H2{C(H)Ph2}2Me-2,6,4).
Ge single bond has been shown to quantitatively reduce CO2 to CO at temperatures as low as −40 °C. The mechanism of this unprecedented reaction has been probed by spectroscopic and computational techniques and involves a metastable intermediate (see picture, Ar*=C6H2{C(H)Ph2}2Me-2,6,4).
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