Carbon disulfide binding at dinuclear and mononuclear nickel complexes ligated by a redox-active ligand: Iminopyridine serving as an accumulator of redox equivalents for the activation of heteroallenes

Carbon disulfide binding at dinuclear and mononuclear nickel complexes ligated by a redox-active ligand: Iminopyridine serving as an accumulator of redox equivalents for the activation of heteroallenes:

Chem. Commun., 2012, Accepted Manuscript
DOI: 10.1039/C2CC34307J, Communication

Amarnath Bheemaraju, Jeffrey W. Beattie, Richard L. Lord, Philip D. Martin, Stanislav Groysman
The dinuclear complex Ni2L1([small eta]2-CS2)2 (2), featuring iminopyridine ligation, is prepared by COD substitutution from Ni2L1COD)2 (1). Spectroscopic, structural, and theoretical data reveals significant activation of the metal-bound C-S bonds, as...
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