Mixed-Valence [FeIFeII] Hydrogenase Active Site Model Complexes Stabilized by a Bidentate Carborane bis-Phosphine Ligand

Mixed-Valence [FeIFeII] Hydrogenase Active Site Model Complexes Stabilized by a Bidentate Carborane bis-Phosphine Ligand:

Dalton Trans., 2012, Accepted Manuscript
DOI: 10.1039/C2DT31192E, Paper

Sascha Ott, Michael Karnahl, Stefanie Tschierlei, Ozlen Erdem, Sonja Pullen, Marie-Pierre Santoni, Edward Reijerse, Wolfgang Lubitz
A series of [FeFe]-hydrogenases active site analogues, with the general formula [Fe2(dt)(CO)4(BC)] 1-3 (dt = dithiolate, pdt = propyl- 1,3-dt (1), bdt = benzene-1,2-dt (2), edt = ethyl-1,2-dt (3); BC...
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