Friday, September 23, 2011

Pentacoordinate iron complexes as functional models of the distal iron in [FeFe] hydrogenases

Pentacoordinate iron complexes as functional models of the distal iron in [FeFe] hydrogenases:

Chem. Commun., 2011, Advance Article
DOI: 10.1039/C1CC14449A, Communication
Maryline Beyler, Salah Ezzaher, Michael Karnahl, Marie-Pierre Santoni, Reiner Lomoth, Sascha Ott
Mononuclear pentacoordinate Fe(II) complexes with a free coordination site were prepared as mimics of the distal Fe (Fed) in the active site of [FeFe] hydrogenases. The complexes catalyze the electrochemical reduction of protons at mild overpotential.
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