Wednesday, September 28, 2011

Wilkinson's iridium acetate trimer as a water-oxidation catalyst

Wilkinson's iridium acetate trimer as a water-oxidation catalyst:

Chem. Commun., 2011, Advance Article
DOI: 10.1039/C1CC15501F, Communication
Alexander R. Parent, James D. Blakemore, Gary W. Brudvig, Robert H. Crabtree
Wilkinson's iridium acetate trimer is a competent precatalyst for water oxidation with NaIO4 but rapidly decomposes using Ce(IV) as a primary oxidant.
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