Binuclear Nickel Complexes with an Edge Sharing Bis(Square-pyramidal) N3Ni(mu-S2)NiN3 Core: Synthesis, Characterization, Crystal Structure and Magnetic Properties

Binuclear Nickel Complexes with an Edge Sharing Bis(Square-pyramidal) N3Ni(mu-S2)NiN3 Core: Synthesis, Characterization, Crystal Structure and Magnetic Properties:

Dalton Trans., 2012, Accepted Manuscript
DOI: 10.1039/C2DT31973J, Paper

Berthold Kersting
The synthesis of the novel macrocyclic octadentate amino-thiophenolate ligand H2L2 (3,7,11,19,23,27-hexaaza-33,34-dithiol-15,31-di(tert-butyl)-tricyclo[27,3,113.17]-tetratriaconta-1(32),13,15,17(34),29,30-hexane) and its ability to support binuclear nickel(II) complexes with dithiolato-bridged square-pyramidal Ni(II) ions is reported. H2L2 is obtained as...
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