Chem. Commun., 2012, Advance Article
DOI: 10.1039/C2CC35304K, Feature Article
DOI: 10.1039/C2CC35304K, Feature Article
Jennifer C. Green, Malcolm L. H. Green, Gerard Parkin
3-Centre 2-electron (3c-2e) interactions can be classified according to whether the pair of electrons are provided by two atoms (Class I) or by one atom (Class II). Recognizing that compounds with symmetrically bridging carbonyl ligands can belong to Class II provides a simple rationalization of the absence of M-M bonds in molecules such as Fe2(CO)9 and [CpFe(CO)2].
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3-Centre 2-electron (3c-2e) interactions can be classified according to whether the pair of electrons are provided by two atoms (Class I) or by one atom (Class II). Recognizing that compounds with symmetrically bridging carbonyl ligands can belong to Class II provides a simple rationalization of the absence of M-M bonds in molecules such as Fe2(CO)9 and [CpFe(CO)2].
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry
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