Synthesis, characterization, and electrochemical properties of diiron propaneditellurolate (PDTe) complexes as the active site models of [FeFe]-hydrogenases

Synthesis, characterization, and electrochemical properties of diiron propaneditellurolate (PDTe) complexes as the active site models of [FeFe]-hydrogenases:

Dalton Trans., 2012, Accepted Manuscript
DOI: 10.1039/C2DT31976D, Paper

Li-Cheng Song, Qianli Li, Zhan-Heng Feng, Xiao-Jing Sun, Zhao-Jun Xie, Haibin Song
Parent complex ([small mu ]-PDTe)Fe2(CO)6 (1, PDTe = [small mu ]-TeCH2CH2CH2Te-[small mu ]) is prepared via a new synthetic route involving reaction of ([small mu ]-Te2)Fe2(CO)6 with Et3BHLi, followed by treatment of ([small mu ]-LiTe)2Fe2(CO)6 with Br(CH2)3Br in 43% yield....
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