Cationic Ti(IV) and neutral Ti(III) titanocene-phosphinoaryloxide frustrated Lewis pairs: hydrogen activation and catalytic amine-borane dehydrogenation

Cationic Ti(IV) and neutral Ti(III) titanocene-phosphinoaryloxide frustrated Lewis pairs: hydrogen activation and catalytic amine-borane dehydrogenation:

Dalton Trans., 2012, Accepted Manuscript
DOI: 10.1039/C2DT30168G, Paper

Duncan Wass
Titanium-phosphorus frustrated Lewis pairs (FLPs) based on titanocene-phosphinoaryloxide complexes have been synthesised. The cationic titanium(IV) complex [Cp2TiOC6H4P(tBu)2][B(C6F5)4] 2 reacts with hydrogen to yield the reduced titanium(III) complex [Cp2TiOC6H4PH(tBu)2][B(C6F5)4] 4. The...
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