Wednesday, March 28, 2012

The inverse sandwich complex [(K(18-crown-6))2Cp][CpFe(CO)2] - Unpredictable redox reactions of [CpFe(CO)2]I with the silanides Na[SiRtBu2] (R = Me, tBu) and the isoelectronic phosphanyl borohydride K[PtBu2BH3]

The inverse sandwich complex [(K(18-crown-6))2Cp][CpFe(CO)2] - Unpredictable redox reactions of [CpFe(CO)2]I with the silanides Na[SiRtBu2] (R = Me, tBu) and the isoelectronic phosphanyl borohydride K[PtBu2BH3]:
Dalton Trans., 2012, Accepted Manuscript
DOI: 10.1039/C2DT00031H, Paper
Hans-Wolfram Lerner
The dimeric iron carbonyl [CpFe(CO)2]2 and the iodosilanes tBu2RSiI were obtained from the reaction of [CpFe(CO)2]I with the silanides Na[SiRtBu2] (R= Me, tBu) in thf. By the reactions of [CpFe(CO)2]I...
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