Encapsulating [FeFe]-hydrogenase model compounds in peptide hydrogels dramatically modifies stability and photochemistry

Encapsulating [FeFe]-hydrogenase model compounds in peptide hydrogels dramatically modifies stability and photochemistry:

Dalton Trans., 2012, Accepted Manuscript
DOI: 10.1039/C2DT30307H, Paper

Pim Wilhelmus Johannes Maria Frederix, Rafal Kania, Joseph A Wright, Dimitrios A Lamprou, Rein Ulijn, C J Pickett, Neil T Hunt
A [FeFe]-hydrogenase model compound ([small micro]-S(CH2)3S)Fe2(CO)4(PMe3)2 [1] has been encapsulated in a Low Molecular Weight (LMW) hydrogelator (Fmoc-Leu-Leu). Linear infrared absorption spectroscopy, gel melting and ultrafast time-resolved infrared spectroscopy experiments reveal...
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