Binding, release, and functionalization of CO2 at a nucleophilic oxo anion complex of titanium

Binding, release, and functionalization of CO2 at a nucleophilic oxo anion complex of titanium: "

Chem. Sci., 2011, 2,1474-1479
DOI: 10.1039/C1SC00215E, Edge Article

Jared S. Silvia, Christopher C. Cummins
It is shown that the binding of CO₂ to a terminal anionic titanium oxide can be reversed chemically, and the isolable carbonate complex can be functionalized with select electrophiles.