Tuesday, July 5, 2011

A stable molecular nickel catalyst for the homogeneous photogeneration of hydrogen in aqueous solution

A stable molecular nickel catalyst for the homogeneous photogeneration of hydrogen in aqueous solution: "

Chem. Commun., 2011, 47,7989-7991
DOI: 10.1039/C1CC12347E, Communication
Matthew P. McLaughlin, Theresa M. McCormick, Richard Eisenberg, Patrick L. Holland
The robust catalyst [Ni(P2PhN2Ph)2](BF4)2 forms H2 (over 2700 turnovers) in water/acetonitrile with a photosensitizer (PS) and ascorbate.
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