Friday, July 15, 2011

A re-investigation of [Fe(L-cysteinate)2(CO)2]2-: an example of non-heme CO coordination of possible relevance to CO binding to ion channel receptors

A re-investigation of [Fe(L-cysteinate)2(CO)2]2-: an example of non-heme CO coordination of possible relevance to CO binding to ion channel receptors: "
Dalton Trans., 2011, Advance Article
DOI: 10.1039/C1DT10338E, Paper
Lindsay Hewison, Tony R. Johnson, Brian E. Mann, Anthony J. H. M. Meijer, Philip Sawle, Roberto Motterlini
The two major isomers of the CO releasing molecule, [Fe(L-cysteinate)2(CO)2], have been identified. Only one isomer is isolated for [Fe(SCH2CH{CO2H}NHCH2)2(CO)2], where the two cysteines are linked.

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