Wednesday, July 27, 2011

The chemistry of hydridocarbonylferrates revisited: syntheses and structures of the new [H2Fe4(CO)12]2- and [HFe5(CO)14]3- anions, and the [Fe(DMF)4][Fe4(CO)12([small mu ]5-[small eta]2-CO)([small mu ]-H)]2 adduct containing an unprecedented isocarbonyl

The chemistry of hydridocarbonylferrates revisited: syntheses and structures of the new [H2Fe4(CO)12]2- and [HFe5(CO)14]3- anions, and the [Fe(DMF)4][Fe4(CO)12([small mu ]5-[small eta]2-CO)([small mu ]-H)]2 adduct containing an unprecedented isocarbonyl: "

Dalton Trans., 2011, Advance Article
DOI: 10.1039/C1DT10648A, Paper
C. Femoni, M. C. Iapalucci, G. Longoni, S. Zacchini
[H2Fe4(CO)12]2- and [HFe5(CO)14]3-, the largest homometallic iron carbonyl, are herein described.
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