Reaction of bis(o-phosphinophenyl)silane with M(PPh3)4 (M = Ni, Pd, Pt): synthesis and structural analysis of [small eta]2-(Si-H) metal(0) and pentacoordinate silyl metal(II) hydride complexes of the Ni triad bearing a PSiP-pincer ligand

Reaction of bis(o-phosphinophenyl)silane with M(PPh3)4 (M = Ni, Pd, Pt): synthesis and structural analysis of [small eta]2-(Si-H) metal(0) and pentacoordinate silyl metal(II) hydride complexes of the Ni triad bearing a PSiP-pincer ligand: "

Dalton Trans., 2011, Advance Article
DOI: 10.1039/C1DT10526D, Paper

Jun Takaya, Nobuharu Iwasawa
Synthesis and structural analysis of [small eta]²-(Si-H) and H-M(II)-Si complexes of group 10 metals were achieved by utilising PSiP-pincer type ligand.
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