Thursday, July 14, 2011

Stoichiometric Reduction of CO2 to CO by Aluminum-Based Frustrated Lewis Pairs

Stoichiometric Reduction of CO2 to CO by Aluminum-Based Frustrated Lewis Pairs: "Thumbnail image of graphical abstract

Reducing frustration: The reaction of Mes3P(CO2)(AlI3)2 in the presence of a CO2 atmosphere results in the formation of Mes3P(CO2)(O(AlI2)2)(AlI3) and [Mes3PI][AlI4] (Mes=2,4,6-Me3C6H2) with the evolution of CO.

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