Friday, August 5, 2011

From amine to ruthenaziridine to azaallyl: unusual transformation of di-(2-pyridylmethyl)amine on ruthenium

From amine to ruthenaziridine to azaallyl: unusual transformation of di-(2-pyridylmethyl)amine on ruthenium: "

Dalton Trans., 2011, Advance Article
DOI: 10.1039/C1DT10626K, Paper
Demyan E. Prokopchuk, Alan J. Lough, Robert H. Morris
The tridentate NNN ligand di-(2-pyridylmethyl)amine has been coordinated to ruthenium, upon which treatment with base affords ruthenaziridine and azaallylruthenium moieties.
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