Reactions of coordinated hydroxymethylphosphines with NH-functional amines: the phosphorus lone pair is crucial for the phosphorus Mannich reaction

Reactions of coordinated hydroxymethylphosphines with NH-functional amines: the phosphorus lone pair is crucial for the phosphorus Mannich reaction: "

Dalton Trans., 2011, Advance Article
DOI: 10.1039/C1DT10586H, Paper

Charles D. Swor, Kyle R. Hanson, Lev N. Zakharov, David R. Tyler
Unlike uncoordinated hydroxymethylphosphines, metal-coordinated hydroxymethylphosphines do not undergo the phosphorus Mannich reaction with amines. Instead, the phosphorus atom's lone pair of electrons must be free for this reaction to occur.
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