Tuesday, August 30, 2011

Synthesis and characterization of diiron dithiolate complexes containing a quinoxaline bridge

Synthesis and characterization of diiron dithiolate complexes containing a quinoxaline bridge:
Dalton Trans., 2011, Advance Article DOI: 10.1039/C1DT10953G
Fenfen Xu, Shaowu Du, Yuping Liu, Jacqueline Hassan, Jie Zhang, Alan M. Bond
A new 2Fe2S complex [Fe2{([small mu ]-CH2S)2R}(CO)6] (1) (R = quinoxaline) has been synthesized. The protonation and redox properties of 1 and its dppm-substituted derivatives 2-4 are also studied.

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