Wednesday, August 24, 2011

Stereomutation in Trigonal-Bipyramidal Systems: A Unified Picture

Stereomutation in Trigonal-Bipyramidal Systems: A Unified Picture: Thumbnail image of graphical abstract

Same difference: Berry pseutorotation (BPR) and Ugi turnstile rotation, which are generally treated as two distinctly different mechanisms for rearrangement of trigonal-bipyramidal structures, have been shown to be equivalent. Alternative mechanisms consist of sequences of pseudorotations proceeding in a single step.

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