Chem. Commun., 2011, Advance Article
DOI: 10.1039/C1CC14150C, Communication
DOI: 10.1039/C1CC14150C, Communication
Takahiro Nishimura, Atsuyuki Kasai, Makoto Nagaosa, Tamio Hayashi
Asymmetric addition of arylboroxines to [small beta]-alkoxyacrylate esters proceeded in the presence of a rhodium/chiral diene complex to give [small beta]-alkoxy-[small beta]-arylcarboxylic acid esters with very high enantioselectivity.
Asymmetric addition of arylboroxines to [small beta]-alkoxyacrylate esters proceeded in the presence of a rhodium/chiral diene complex to give [small beta]-alkoxy-[small beta]-arylcarboxylic acid esters with very high enantioselectivity.
Fc does nothing. This group specializes in chiral dienes as asymmetric spectator ligands
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