Friday, August 19, 2011

Iron(II) template synthesis of benzannulated triphospha- and triarsamacrocycles

Iron(II) template synthesis of benzannulated triphospha- and triarsamacrocycles:

Dalton Trans., 2011, Advance Article
DOI: 10.1039/C0DT01724H, Paper
Thomas Albers, Julia Baker (nee Johnstone), Simon J. Coles, Peter G. Edwards, Benson Kariuki, Paul D. Newman
New 9-membered benzannulated tridentate phosphorus and arsenic macrocycles are formed in high yield by the base promoted nucleophilic displacement of F- in 2-fluorophenyl phosphines on a CpFe+ template.
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