Monday, August 15, 2011

Pt(II)-activated coupling of aminoethylferrocene with benzonitrile. A facile access route to a new redox-active bis(ferrocenyl-amidine) anion sensor


Chem. Commun., 2011, Advance Article
DOI: 10.1039/C1CC13704B, Communication
Daniel Nieto, Ana Ma Gonzalez-Vadillo, Sonia Bruna, Cesar J. Pastor, Angel E. Kaifer, Isabel Cuadrado
A new redox-active bis(ferrocenyl-amidine) H2PO4- anion sensor has been prepared via Pt(II)-mediated nucleophilic addition of [small beta]-aminoethylferrocene to a benzonitrile ligand.
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1 comment:

  1. Tom RauchfussAugust 16, 2011 at 9:17 AM

    Their methodology uses FcCH2+ chemistry, like ours. In future work, one can expect to see thiourea-based modules attached to Fc.

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